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CAS NO.99768-12-4
1(10-100)Metric Ton1(10-100)Metric Ton
| Methyl 4-boronobenzoate Basic information |
| Product Name: | Methyl 4-boronobenzoate |
| Synonyms: | RARECHEM AH PB 0115;P-(METHOXYCARBONYL)PHENYLBORONIC ACID;METHYL 4-BORONOBENZOATE;AKOS BRN-0122;4-METHOXYCARBONYLBENZENEBORONIC ACID;4-METHOXYCARBONYLPHENYLBORONIC ACID;4-CARBOMETHOXYPHENYLBORONIC ACID;4-METHOXYCATBONYLPHENYLBORONICACID |
| CAS: | 99768-12-4 |
| MF: | C8H9BO4 |
| MW: | 179.97 |
| EINECS: | |
| Product Categories: | blocks;BoronicAcids;Carboxes;Boronic Acid series;Acids and Derivatives;Boron, Nitrile, Thio,& TM-Cpds;Boronic acids;Aryl;Boronic acid;Organoborons;B (Classes of Boron Compounds);CHIRAL CHEMICALS;Aryl Boronic Acids;Boronic Acids and Derivatives;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organometallic Reagents;Boronate Ester;Potassium Trifluoroborate |
| Mol File: | 99768-12-4.mol |
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| Methyl 4-boronobenzoate Chemical Properties |
| mp | 197-200 °C(lit.) |
| storage temp. | 0-6°C |
| CAS DataBase Reference | 99768-12-4(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 37/39-26 |
| WGK Germany | 3 |
| HazardClass | IRRITANT |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| Methyl 4-boronobenzoate Usage And Synthesis |
| Chemical Properties | White to light yellow crystal powde |
| Usage | Reagent used for• ;Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence1 • ;Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides2 • ;One-pot ipso-nitration of arylboronic acids3 • ;Copper-catalyzed nitration4 • ;Cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling5 • ;Reagent used in Preparation of• ;Biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6† • ;Chromenones and their |
| Usage | suzuki reaction |
| Methyl 4-boronobenzoate Preparation Products And Raw materials |
| Raw materials | Methanol-->Tetrahydrofuran-->Nitrogen-->Potassium permanganate-->Magnesium-->Trimethyl borate-->4-Bromotoluene |
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