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CAS NO.97-99-4
Product Name: | Tetrahydrofurfuryl alcohol |
Synonyms: | (tetrahydro-furan-2-yl)-methanol;2-Furanmethanol,tetrahydro-;2-Hydroxymethyl-Tetrahydrofuran;alpha-Tetrahydrofurfuryl alcohol;Furfuryl alcohol, tetrahydro-;Oxolan-2-methanol;Qo tetrahydrofurfuryl alcohol;Qo thfa |
CAS: | 97-99-4 |
MF: | C5H10O2 |
MW: | 102.13 |
EINECS: | 202-625-6 |
Product Categories: | Furan&Benzofuran;Furans;Building Blocks;C4 to C7;Chemical Synthesis;Heterocyclic Building Blocks;fine chemical;Solvent for fats, waxes, resins, in organic synthesis. |
Mol File: | 97-99-4.mol |
Tetrahydrofurfuryl alcohol Chemical Properties |
mp | -80 °C |
bp | 178 °C(lit.) |
density | 1.0543 |
vapor density | 3.52 (vs air) |
vapor pressure | 2.3 mm Hg ( 39 °C) |
FEMA | 3056 |
refractive index |
n |
Fp | 183 °F |
Water Solubility | soluble |
Sensitive | Hygroscopic |
Merck | 14,9213 |
BRN | 102723 |
CAS DataBase Reference | 97-99-4(CAS DataBase Reference) |
NIST Chemistry Reference | 2-Furanmethanol, tetrahydro-(97-99-4) |
EPA Substance Registry System | 2-Furanmethanol, tetrahydro-(97-99-4) |
Safety Information |
Hazard Codes | Xi,T |
Risk Statements | 36-62-61 |
Safety Statements | 39-36/37/39 |
WGK Germany | 2 |
RTECS | LU2450000 |
HS Code | 29321300 |
Hazardous Substances Data | 97-99-4(Hazardous Substances Data) |
MSDS Information |
Provider | Language |
---|---|
THFA | English |
SigmaAldrich | English |
ACROS | English |
ALFA | English |
Tetrahydrofurfuryl alcohol Usage And Synthesis |
Chemical Properties | Colorless to light yellow liqui |
General Description | A clear colorless liquid with a mild odor. Flash point 167°F. Vapors are heavier than air. |
Air & Water Reactions | Denser than water and soluble in water. |
Reactivity Profile | Acetyl bromide reacts violently with alcohols or water [Merck 11th ed. 1989]. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73. 1967; J, Org. Chem. 28:1893. 1963]. Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous- carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites [NFPA 491 M 1991]. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969]. |
Health Hazard | Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. |
Tetrahydrofurfuryl alcohol Preparation Products And Raw materials |
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2.Material Safety Data Sheet (MSDS)
3.Route of synthesis (ROS)
4.Method of Aanlysis(MOA)
5.Nuclear Magnetic Resonance(NMR)
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Product Name: | Tetrahydrofurfuryl alcohol |
Synonyms: | (tetrahydro-furan-2-yl)-methanol;2-Furanmethanol,tetrahydro-;2-Hydroxymethyl-Tetrahydrofuran;alpha-Tetrahydrofurfuryl alcohol;Furfuryl alcohol, tetrahydro-;Oxolan-2-methanol;Qo tetrahydrofurfuryl alcohol;Qo thfa |
CAS: | 97-99-4 |
MF: | C5H10O2 |
MW: | 102.13 |
EINECS: | 202-625-6 |
Product Categories: | Furan&Benzofuran;Furans;Building Blocks;C4 to C7;Chemical Synthesis;Heterocyclic Building Blocks;fine chemical;Solvent for fats, waxes, resins, in organic synthesis. |
Mol File: | 97-99-4.mol |
Tetrahydrofurfuryl alcohol Chemical Properties |
mp | -80 °C |
bp | 178 °C(lit.) |
density | 1.0543 |
vapor density | 3.52 (vs air) |
vapor pressure | 2.3 mm Hg ( 39 °C) |
FEMA | 3056 |
refractive index |
n |
Fp | 183 °F |
Water Solubility | soluble |
Sensitive | Hygroscopic |
Merck | 14,9213 |
BRN | 102723 |
CAS DataBase Reference | 97-99-4(CAS DataBase Reference) |
NIST Chemistry Reference | 2-Furanmethanol, tetrahydro-(97-99-4) |
EPA Substance Registry System | 2-Furanmethanol, tetrahydro-(97-99-4) |
Safety Information |
Hazard Codes | Xi,T |
Risk Statements | 36-62-61 |
Safety Statements | 39-36/37/39 |
WGK Germany | 2 |
RTECS | LU2450000 |
HS Code | 29321300 |
Hazardous Substances Data | 97-99-4(Hazardous Substances Data) |
MSDS Information |
Provider | Language |
---|---|
THFA | English |
SigmaAldrich | English |
ACROS | English |
ALFA | English |
Tetrahydrofurfuryl alcohol Usage And Synthesis |
Chemical Properties | Colorless to light yellow liqui |
General Description | A clear colorless liquid with a mild odor. Flash point 167°F. Vapors are heavier than air. |
Air & Water Reactions | Denser than water and soluble in water. |
Reactivity Profile | Acetyl bromide reacts violently with alcohols or water [Merck 11th ed. 1989]. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73. 1967; J, Org. Chem. 28:1893. 1963]. Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous- carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites [NFPA 491 M 1991]. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969]. |
Health Hazard | Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. |
Tetrahydrofurfuryl alcohol Preparation Products And Raw materials |