Product information

Allylboronic acid pinacol ester Basic information

Product Name:	Allylboronic acid pinacol ester
Synonyms:	PINACOL ALLYLBORONATE;2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;ALLYLBORONIC ACID, PINACOL CYCLIC ESTER;ALLYLBORONIC ACID PINACOL ESTER;AKOS BRN-1082;ALLBORONIC ACID,PINACOL CYCLIC ESTER;Allylboronic acid piracol ester;Allylboronic acid pinacol ester, 98+%
CAS:	72824-04-5
MF:	C9H17BO2
MW:	168.04
EINECS:	-0
Product Categories:	Olefin;Organoborons;B (Classes of Boron Compounds);Boronic Acids Esters;CHIRAL CHEMICALS;Alkyl Boronate Esters;Boronate Esters;Boronic Acids and Derivatives;Chemical Synthesis;Organometallic Reagents
Mol File:	72824-04-5.mol

Allylboronic acid pinacol ester Chemical Properties

bp	50-53 °C5 mm Hg(lit.)
density	0.896 g/mL at 25 °C(lit.)
refractive index	n20/D 1.4268(lit.)
Fp	115 °F
storage temp.	Refrigerator
BRN	4244068
CAS DataBase Reference	72824-04-5(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	10-36/37/38
Safety Statements	26-36
RIDADR	UN 1993 3/PG 3
WGK Germany	3
Hazard Note	Irritant
HazardClass	3
PackingGroup	III
HS Code	29310095

MSDS Information

Provider	Language
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane	English
SigmaAldrich	English
ALFA	English

Allylboronic acid pinacol ester Usage And Synthesis

Chemical Properties

Clear corless liquid

Usage

Reagent used for• ;Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis1 • ;Intermolecular radical additions2 • ;Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids3 • ;Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes4 • ;Nucleic acid-templated energy transfer leading to a photorelease reaction5 • ;Stereoselective indium-catalyzed Hosomi-Sakurai reactions6 Reagent used in Preparation of• ;Cyclic sulfone hydroxyethylamines as BACE1 inhibitors for reduction o

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