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CAS NO.60-12-8
| Phenethyl alcohol Basic information |
| Product Name: | Phenethyl alcohol |
| Synonyms: | RARECHEM AL BD 0140;PHENYL ETHYL ALCHOL;PHENYL ETHYL ALCOHOL;PHENYL ETHANOL;PHENYLETHANOL,2-;PHENETHYL ALCOHOL;(beta-pea);.beta.-Phenylethanol |
| CAS: | 60-12-8 |
| MF: | C8H10O |
| MW: | 122.16 |
| EINECS: | 200-456-2 |
| Product Categories: | Miscellaneous;Aromatics;Miscellaneous Reagents;Alcohols;Aspalathus linearis (Rooibos tea);Building Blocks;C7 to C8;Chemical Synthesis;Citrus aurantium (Seville orange);Humulus lupulus (Hops);Nutrition Research;Ocimum basilicum (Basil);Organic Building Blocks;Oxygen Compounds;Phytochemicals by Plant (Food/Spice/Herb);Sambucus nigra (Elderberry);Vaccinium myrtillus (Bilberry) |
| Mol File: | 60-12-8.mol |
|
|
|
| Phenethyl alcohol Chemical Properties |
| mp | −27 °C(lit.) |
| bp | 219-221 °C750 mm Hg(lit.) |
| density | 1.020 g/mL at 20 °C(lit.) |
| vapor density | 4.21 (vs air) |
| vapor pressure | 1 mm Hg ( 58 °C) |
| FEMA | 2858 |
| refractive index |
n |
| Fp | 216 °F |
| storage temp. | Store at RT. |
| Water Solubility | 20 g/L (20 ºC) |
| Merck | 14,7224 |
| BRN | 1905732 |
| Stability: | Stable. Substances to be avoided include strong acids and strong oxidizing agents. Combustible. |
| CAS DataBase Reference | 60-12-8(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzeneethanol(60-12-8) |
| EPA Substance Registry System | Benzeneethanol(60-12-8) |
| Safety Information |
| Hazard Codes | Xn |
| Risk Statements | 21/22-36/38-36-22 |
| Safety Statements | 26-28-36/37-36/37/39 |
| RIDADR | UN 2810 6.1/PG 3 |
| WGK Germany | 1 |
| RTECS | SG7175000 |
| HazardClass | 6.1 |
| PackingGroup | III |
| Hazardous Substances Data | 60-12-8(Hazardous Substances Data) |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| Phenethyl alcohol Usage And Synthesis |
| Edible spices |
Phenethyl alcohol is a kind of edible spices, and naturally exists in neroli, rose oil, geranium oil and other oils, because it has a soft, pleasant and persistent rose fragrance and is widely used in various kinds of flavors and cigarette flavor. It is dispensing rose scent, food additives, the main raw material for rose scent flavor, stable on alkali, which are widely used in soap fragrance, is essence blending all rose scent series of spices, because it does not dissolve in water, it is often used in the making up water, soap and orange flower, purple, etc. It is also used in the blending of flavor. Because the phenethyl alcohol has a good antibacterial efficiency, it can be used in the ophthalmic solution. At present there are main three synthesis methods as following: 1, by styrene via halogenation, saponification, hydrogenation, distillation. 2, and microorganism fermentation in yeast by bioconversion. 3, calcium carbide, benzene as raw material preparation of benzyl ethanol, reaction equations are as follows: 1)CaC2+2H2O=Ca(OH)2+C2H2 2)C6H6+C2H2=C6H6CHCH2（Styrene） 3)C6H6CHCH2＋H2O=C6H6CH2CH2OH（Phenethyl alcohol） |
| Reference quality standards |
1. appearance: colorless transparent liquid, colour and lustre is not more than 4 # color code 2. aroma: rose aroma 3. relative density (25/25 ℃) : 1.017 to 1.020 4. refractive index (20 ℃) : 1.5310 to 1.5340 5. solubility (25 ℃) : 1 ml sample completely dissolved in 2 ml50 % ethanol, soluble in 50 times the volume of distilled water is clear solution 6. alcohol content: 99.0% (99.5% or higher internal control chemical method, chromatography peaks above 99.7%) 7. chloride content test: pass 8. arsenic content: 3 PPM or less (0.0003%). 9. heavy metals: 10 PPM or less (0.001%) USP23 version of standard and food additives standard QB/T3786-99 countries The above information is edited by the chemicalbook of Duan Yalan. |
| Content Analysis | According to the total amount of alcohol assay (OT - 5). Taken by acetylation sample quantity is 1 g. Calculation of the equivalent factor (e) 61.08. |
| toxicity | LD50 (1580 ~ 2020) of 1790 mg/kg (rats, through the mouth). |
| Limited use | FEMA (mg/kg) : soft drinks; 1.5 Cold drink 8.3; Candy 12; Baked goods 16; The pudding class 0.15; Gum 21 ~ 80. |
| Chemical property | Colorless liquid with rose fragrance. Soluble in ethanol, ethyl ether, glycerin, slightly soluble in water, slightly soluble in mineral oil. |
| Application |
Phenethyl alcohol is China's regulation edible spice, dosage according to the normal production needs. Generally in 13 sweet sugar 21 to 80 mg/kg; Baked goods in 16 mg/kg; Candy in 12 mg/kg; Cold drinks in 8.3 mg/kg. GB 2760-1996 rules to allow the use of edible spices. To make honey, bread, peaches and berries such as type of essence. Allocate rose scent flower essential oil and a variety of floral fragrance, such as jasmine scent, clove, orange flower scent, scent can allocate almost all of the essential oils, widely used in the deployment of soap and cosmetics fragrance. In addition, also can mix all kinds of edible flavor, such as strawberry, peach, plum, melon, caramel, honey is sweet, cream type edible flavor, etc. |
| Category | Inflammable Liquid |
| Toxicity classification | Poisoning |
| Acute toxity | Oral - LD50 in rats: 1790 mg/kg |
| Stimulate data | Skin - moderate rabbit 100 mg / 24 hours; Severe eye - rabbit 0.75 mg / 24 hours |
| Flammability hazard characteristics | Flammable. Combustion produces stimulation of smoke. |
| Transportation and storing characteristics | Warehouse ventilation, dry at low temperature. |
| Extinguishing agent | Dry powder, foam, sandy soil, and water |
| Chemical Properties | colourless liquid |
| Usage | antibacterial |
| Phenethyl alcohol Preparation Products And Raw materials |
| Phenethyl alcohol Basic information |
| Product Name: | Phenethyl alcohol |
| Synonyms: | RARECHEM AL BD 0140;PHENYL ETHYL ALCHOL;PHENYL ETHYL ALCOHOL;PHENYL ETHANOL;PHENYLETHANOL,2-;PHENETHYL ALCOHOL;(beta-pea);.beta.-Phenylethanol |
| CAS: | 60-12-8 |
| MF: | C8H10O |
| MW: | 122.16 |
| EINECS: | 200-456-2 |
| Product Categories: | Miscellaneous;Aromatics;Miscellaneous Reagents;Alcohols;Aspalathus linearis (Rooibos tea);Building Blocks;C7 to C8;Chemical Synthesis;Citrus aurantium (Seville orange);Humulus lupulus (Hops);Nutrition Research;Ocimum basilicum (Basil);Organic Building Blocks;Oxygen Compounds;Phytochemicals by Plant (Food/Spice/Herb);Sambucus nigra (Elderberry);Vaccinium myrtillus (Bilberry) |
| Mol File: | 60-12-8.mol |
|
|
|
| Phenethyl alcohol Chemical Properties |
| mp | −27 °C(lit.) |
| bp | 219-221 °C750 mm Hg(lit.) |
| density | 1.020 g/mL at 20 °C(lit.) |
| vapor density | 4.21 (vs air) |
| vapor pressure | 1 mm Hg ( 58 °C) |
| FEMA | 2858 |
| refractive index |
n |
| Fp | 216 °F |
| storage temp. | Store at RT. |
| Water Solubility | 20 g/L (20 ºC) |
| Merck | 14,7224 |
| BRN | 1905732 |
| Stability: | Stable. Substances to be avoided include strong acids and strong oxidizing agents. Combustible. |
| CAS DataBase Reference | 60-12-8(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzeneethanol(60-12-8) |
| EPA Substance Registry System | Benzeneethanol(60-12-8) |
| Safety Information |
| Hazard Codes | Xn |
| Risk Statements | 21/22-36/38-36-22 |
| Safety Statements | 26-28-36/37-36/37/39 |
| RIDADR | UN 2810 6.1/PG 3 |
| WGK Germany | 1 |
| RTECS | SG7175000 |
| HazardClass | 6.1 |
| PackingGroup | III |
| Hazardous Substances Data | 60-12-8(Hazardous Substances Data) |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| Phenethyl alcohol Usage And Synthesis |
| Edible spices |
Phenethyl alcohol is a kind of edible spices, and naturally exists in neroli, rose oil, geranium oil and other oils, because it has a soft, pleasant and persistent rose fragrance and is widely used in various kinds of flavors and cigarette flavor. It is dispensing rose scent, food additives, the main raw material for rose scent flavor, stable on alkali, which are widely used in soap fragrance, is essence blending all rose scent series of spices, because it does not dissolve in water, it is often used in the making up water, soap and orange flower, purple, etc. It is also used in the blending of flavor. Because the phenethyl alcohol has a good antibacterial efficiency, it can be used in the ophthalmic solution. At present there are main three synthesis methods as following: 1, by styrene via halogenation, saponification, hydrogenation, distillation. 2, and microorganism fermentation in yeast by bioconversion. 3, calcium carbide, benzene as raw material preparation of benzyl ethanol, reaction equations are as follows: 1)CaC2+2H2O=Ca(OH)2+C2H2 2)C6H6+C2H2=C6H6CHCH2（Styrene） 3)C6H6CHCH2＋H2O=C6H6CH2CH2OH（Phenethyl alcohol） |
| Reference quality standards |
1. appearance: colorless transparent liquid, colour and lustre is not more than 4 # color code 2. aroma: rose aroma 3. relative density (25/25 ℃) : 1.017 to 1.020 4. refractive index (20 ℃) : 1.5310 to 1.5340 5. solubility (25 ℃) : 1 ml sample completely dissolved in 2 ml50 % ethanol, soluble in 50 times the volume of distilled water is clear solution 6. alcohol content: 99.0% (99.5% or higher internal control chemical method, chromatography peaks above 99.7%) 7. chloride content test: pass 8. arsenic content: 3 PPM or less (0.0003%). 9. heavy metals: 10 PPM or less (0.001%) USP23 version of standard and food additives standard QB/T3786-99 countries The above information is edited by the chemicalbook of Duan Yalan. |
| Content Analysis | According to the total amount of alcohol assay (OT - 5). Taken by acetylation sample quantity is 1 g. Calculation of the equivalent factor (e) 61.08. |
| toxicity | LD50 (1580 ~ 2020) of 1790 mg/kg (rats, through the mouth). |
| Limited use | FEMA (mg/kg) : soft drinks; 1.5 Cold drink 8.3; Candy 12; Baked goods 16; The pudding class 0.15; Gum 21 ~ 80. |
| Chemical property | Colorless liquid with rose fragrance. Soluble in ethanol, ethyl ether, glycerin, slightly soluble in water, slightly soluble in mineral oil. |
| Application |
Phenethyl alcohol is China's regulation edible spice, dosage according to the normal production needs. Generally in 13 sweet sugar 21 to 80 mg/kg; Baked goods in 16 mg/kg; Candy in 12 mg/kg; Cold drinks in 8.3 mg/kg. GB 2760-1996 rules to allow the use of edible spices. To make honey, bread, peaches and berries such as type of essence. Allocate rose scent flower essential oil and a variety of floral fragrance, such as jasmine scent, clove, orange flower scent, scent can allocate almost all of the essential oils, widely used in the deployment of soap and cosmetics fragrance. In addition, also can mix all kinds of edible flavor, such as strawberry, peach, plum, melon, caramel, honey is sweet, cream type edible flavor, etc. |
| Category | Inflammable Liquid |
| Toxicity classification | Poisoning |
| Acute toxity | Oral - LD50 in rats: 1790 mg/kg |
| Stimulate data | Skin - moderate rabbit 100 mg / 24 hours; Severe eye - rabbit 0.75 mg / 24 hours |
| Flammability hazard characteristics | Flammable. Combustion produces stimulation of smoke. |
| Transportation and storing characteristics | Warehouse ventilation, dry at low temperature. |
| Extinguishing agent | Dry powder, foam, sandy soil, and water |
| Chemical Properties | colourless liquid |
| Usage | antibacterial |
| Phenethyl alcohol Preparation Products And Raw materials |