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CAS NO.2937-50-0
Allyl chloroformate Basic information |
Product Name: | Allyl chloroformate |
Synonyms: | 2-propenylchloroformate;ALLYLCHLOROFORMATE(ACF);allylesterkyselinychlormravenci;carbonochloridicacid,2-propenylester;chlorocarbonicacidallylester;chloro-formicaciallylester;CHLOROFORMIC ACID ALLYL ESTER;ALLYL CHLOROCARBONATE |
CAS: | 2937-50-0 |
MF: | C4H5ClO2 |
MW: | 120.53 |
EINECS: | 220-916-6 |
Product Categories: | Pharmaceutical Intermediates;CHLOROFORMATES;Amine ProtectionProtection and Derivatization;Others;Peptide Synthesis;Protecting and Derivatizing Reagents;Specialty Synthesis |
Mol File: | 2937-50-0.mol |
Allyl chloroformate Chemical Properties |
mp | 106℃ |
bp | 109 °C |
density | 1.134 g/mL at 20 °C(lit.) |
vapor pressure | 3.67 psi ( 20 °C) |
refractive index |
n |
Fp | 88 °F |
storage temp. | 2-8°C |
CAS DataBase Reference | 2937-50-0(CAS DataBase Reference) |
NIST Chemistry Reference | Allyl chloroformate(2937-50-0) |
EPA Substance Registry System | Carbonochloridic acid, 2-propenyl ester(2937-50-0) |
Safety Information |
Hazard Codes | T+ |
Risk Statements | 10-22-26-34 |
Safety Statements | 26-28-36/37/39-45 |
RIDADR | UN 1722 6.1/PG 1 |
WGK Germany | 3 |
RTECS | LQ5775000 |
F | 19 |
HazardClass | 6.1(b) |
PackingGroup | I |
Hazardous Substances Data | 2937-50-0(Hazardous Substances Data) |
MSDS Information |
Provider | Language |
---|---|
Allyl chloroformate | English |
SigmaAldrich | English |
ACROS | English |
ALFA | English |
Allyl chloroformate Usage And Synthesis |
Chemical Properties | Colorless liquid |
General Description | A colorless liquid with a pungent odor. Flash point 88°F. Corrosive to metals and tissue. Very toxic by inhalation, ingestion and/or skin contact. Vapors are heavier than air. |
Air & Water Reactions | Highly flammable. Water reaction produces heat and acidic HCl. In the presence of moist air, corrosive hydrogen chloride is produced. |
Reactivity Profile | Acid halides, such as Allyl chloroformate, are water reactive; some are violently reactive. They are incompatible with strong oxidizing agents, alcohols, amines, alkali. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. |
Health Hazard | Vapor irritates eyes and respiratory tract. Contact with liquid causes eye and skin irritation, and ingestion irritates mouth and stomach. |
Allyl chloroformate Preparation Products And Raw materials |
Allyl chloroformate Basic information |
Product Name: | Allyl chloroformate |
Synonyms: | 2-propenylchloroformate;ALLYLCHLOROFORMATE(ACF);allylesterkyselinychlormravenci;carbonochloridicacid,2-propenylester;chlorocarbonicacidallylester;chloro-formicaciallylester;CHLOROFORMIC ACID ALLYL ESTER;ALLYL CHLOROCARBONATE |
CAS: | 2937-50-0 |
MF: | C4H5ClO2 |
MW: | 120.53 |
EINECS: | 220-916-6 |
Product Categories: | Pharmaceutical Intermediates;CHLOROFORMATES;Amine ProtectionProtection and Derivatization;Others;Peptide Synthesis;Protecting and Derivatizing Reagents;Specialty Synthesis |
Mol File: | 2937-50-0.mol |
Allyl chloroformate Chemical Properties |
mp | 106℃ |
bp | 109 °C |
density | 1.134 g/mL at 20 °C(lit.) |
vapor pressure | 3.67 psi ( 20 °C) |
refractive index |
n |
Fp | 88 °F |
storage temp. | 2-8°C |
CAS DataBase Reference | 2937-50-0(CAS DataBase Reference) |
NIST Chemistry Reference | Allyl chloroformate(2937-50-0) |
EPA Substance Registry System | Carbonochloridic acid, 2-propenyl ester(2937-50-0) |
Safety Information |
Hazard Codes | T+ |
Risk Statements | 10-22-26-34 |
Safety Statements | 26-28-36/37/39-45 |
RIDADR | UN 1722 6.1/PG 1 |
WGK Germany | 3 |
RTECS | LQ5775000 |
F | 19 |
HazardClass | 6.1(b) |
PackingGroup | I |
Hazardous Substances Data | 2937-50-0(Hazardous Substances Data) |
MSDS Information |
Provider | Language |
---|---|
Allyl chloroformate | English |
SigmaAldrich | English |
ACROS | English |
ALFA | English |
Allyl chloroformate Usage And Synthesis |
Chemical Properties | Colorless liquid |
General Description | A colorless liquid with a pungent odor. Flash point 88°F. Corrosive to metals and tissue. Very toxic by inhalation, ingestion and/or skin contact. Vapors are heavier than air. |
Air & Water Reactions | Highly flammable. Water reaction produces heat and acidic HCl. In the presence of moist air, corrosive hydrogen chloride is produced. |
Reactivity Profile | Acid halides, such as Allyl chloroformate, are water reactive; some are violently reactive. They are incompatible with strong oxidizing agents, alcohols, amines, alkali. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. |
Health Hazard | Vapor irritates eyes and respiratory tract. Contact with liquid causes eye and skin irritation, and ingestion irritates mouth and stomach. |
Allyl chloroformate Preparation Products And Raw materials |