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CAS NO.141-97-9
| Ethyl Acetoacetate |
| Product name: | Ethyl Acetoacetate |
| CAS No.: | 141-97-9 |
| EINECS NO: | 205-516-1 |
| Formula: | C6H10O3 |
| Structure Formula: |
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| M.W.： | 130.14 |
| Characters: |
Colorless clarified liquid with cheerful fruit smell. It is easy soluble in ethanol, ethyl ether, propylene glycol and ethyl acetate, and soluble in water as 1:12. Boiling point: 181 ℃, melting point: -45 ℃ (enol: -80 ℃, ketone: -39 ℃), flash point: 84.5 ℃. |
| Main Uses: |
It is mainly used for medicine, dyes, pesticides, etc.. It also can be used in food additives and flavors and perfumes. |
| Ethyl acetoacetate Basic information |
| Product Name: | Ethyl acetoacetate |
| Synonyms: | FEMA 2415;LABOTEST-BB LT01690211;EAA;ETHYL 3-OXOBUTANATE;ETHYL 3-OXOBUTANOATE;ETHYL 3-OXOBUTANOIC ACID;ETHYL 3-OXOBUTYRATE;ETHYL 3-KETOBUTANOATE |
| CAS: | 141-97-9 |
| MF: | C6H10O3 |
| MW: | 130.14 |
| EINECS: | 205-516-1 |
| Product Categories: | Pharmaceutical Intermediates;Organics;API intermediates;Miscellaneous;ester Flavor;Analytical Reagents;Analytical Reagents for General Use;Analytical/Chromatography;Building Blocks;C6 to C7;Carbonyl Compounds;Chemical Synthesis;E-H;Esters;Organic Building Blocks;Puriss p.a.;Organic synthesis;Solvent |
| Mol File: | 141-97-9.mol |
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| Ethyl acetoacetate Chemical Properties |
| mp | −43 °C(lit.) |
| bp | 181 °C(lit.) |
| density | 1.029 g/mL at 20 °C(lit.) |
| vapor density | 4.48 (vs air) |
| vapor pressure | 1 mm Hg ( 28.5 °C) |
| refractive index |
n |
| FEMA | 2415 |
| Fp | 185 °F |
| solubility | 116 g/L (20°C) |
| Water Solubility | 116 g/L (20 ºC) |
| Merck | 14,3758 |
| BRN | 385838 |
| Stability: | Stable. Incompatible with acids, bases, oxidizing agents, reducing agents, alkali metals. Combustible. |
| CAS DataBase Reference | 141-97-9(CAS DataBase Reference) |
| NIST Chemistry Reference | Butanoic acid, 3-oxo-, ethyl ester(141-97-9) |
| EPA Substance Registry System | Butanoic acid, 3-oxo-, ethyl ester(141-97-9) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36 |
| Safety Statements | 26-24/25 |
| RIDADR | UN 1993 |
| WGK Germany | 1 |
| RTECS | AK5250000 |
| HazardClass | 3.2 |
| PackingGroup | III |
| Hazardous Substances Data | 141-97-9(Hazardous Substances Data) |
| Ethyl acetoacetate Usage And Synthesis |
| Chemical Properties | Colourless, clear liquid |
| Usage | Ethyl acetoacetate (EAA) is used as starting material for the syntheses of alpha-substituted acetoacetic esters and cyclic compounds, e.g. pyrazole, pyrimidine and coumarin derivatives as well as intermediate for vitamins and pharmaceuticals. Product Data Sheet |
| General Description | A colorless liquid with a fruity odor. Flash point 185°F. Boiling point 365°F. May cause adverse health effects if ingested or inhaled. May irritate to skin, eyes and mucous membranes. Used in organic synthesis and in lacquers and paints. |
| Air & Water Reactions | Flammable. |
| Reactivity Profile | Ethyl acetoacetate, a beta-keto ester, is more reactive than many esters. Undergoes an exothermic cleavage reaction in the presence of concentrated base. Reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Mixing with 2,2,2-tris(bromomethyl)ethanol and zinc led to an explosion [US Patent 3 578 619, Crotonaldehyde may rapidly polymerize with Ethyl acetoacetate (Soriano, D.S. et al. 1988. Journal of Chemical Education 65:637.).1971]. |
| Health Hazard | Liquid may cause mild irritation of eyes. |
| Ethyl acetoacetate Preparation Products And Raw materials |
