Name: 141-97-9 C6H10O3 Ethyl acetoacetate
SKU: 141-97-9
Availability: InStock

Keywords

141-97-9 C6H10O3 Ethyl acetoacetate
141-97-9
C6H10O3

Quick Details

ProName: 141-97-9 C6H10O3 Ethyl aceto...
CasNo: 141-97-9
Molecular Formula: C6H10O3
Appearance: white powder
Application: Pharmaceutical Intermediates;Organics;...
DeliveryTime: 5-7 days after payment
PackAge: Woven bag
Port: Tianjin Shanghai
ProductionCapacity: 1 Kilogram/Day
Purity: 99%
Storage: Normal temperature
Transportation: Ocean shipping Express delivery
LimitNum: 10 Gram

Superiority

Ethyl acetoacetate Basic information

Product Name:	Ethyl acetoacetate
Synonyms:	FEMA 2415;LABOTEST-BB LT01690211;EAA;ETHYL 3-OXOBUTANATE;ETHYL 3-OXOBUTANOATE;ETHYL 3-OXOBUTANOIC ACID;ETHYL 3-OXOBUTYRATE;ETHYL 3-KETOBUTANOATE
CAS:	141-97-9
MF:	C6H10O3
MW:	130.14
EINECS:	205-516-1
Product Categories:	Pharmaceutical Intermediates;Organics;API intermediates;Miscellaneous;ester Flavor;Analytical Reagents;Analytical Reagents for General Use;Analytical/Chromatography;Building Blocks;C6 to C7;Carbonyl Compounds;Chemical Synthesis;E-H;Esters;Organic Building Blocks;Puriss p.a.;Organic synthesis;Solvent
Mol File:	141-97-9.mol

Ethyl acetoacetate Chemical Properties

mp	−43 °C(lit.)
bp	181 °C(lit.)
density	1.029 g/mL at 20 °C(lit.)
vapor density	4.48 (vs air)
vapor pressure	1 mm Hg ( 28.5 °C)
refractive index	n20/D 1.419
FEMA	2415
Fp	185 °F
solubility	116 g/L (20°C)
Water Solubility	116 g/L (20 ºC)
Merck	14,3758
BRN	385838
Stability:	Stable. Incompatible with acids, bases, oxidizing agents, reducing agents, alkali metals. Combustible.
CAS DataBase Reference	141-97-9(CAS DataBase Reference)
NIST Chemistry Reference	Butanoic acid, 3-oxo-, ethyl ester(141-97-9)
EPA Substance Registry System	Butanoic acid, 3-oxo-, ethyl ester(141-97-9)

Safety Information

Hazard Codes	Xi
Risk Statements	36
Safety Statements	26-24/25
RIDADR	UN 1993
WGK Germany	1
RTECS	AK5250000
HazardClass	3.2
PackingGroup	III
Hazardous Substances Data	141-97-9(Hazardous Substances Data)

MSDS Information

Provider	Language
Acetoacetic ester	English
SigmaAldrich	English
ACROS	English
ALFA	English

Ethyl acetoacetate Usage And Synthesis

Chemical Properties	Colourless, clear liquid
Usage	Ethyl acetoacetate (EAA) is used as starting material for the syntheses of alpha-substituted acetoacetic esters and cyclic compounds, e.g. pyrazole, pyrimidine and coumarin derivatives as well as intermediate for vitamins and pharmaceuticals. Product Data Sheet
General Description	A colorless liquid with a fruity odor. Flash point 185°F. Boiling point 365°F. May cause adverse health effects if ingested or inhaled. May irritate to skin, eyes and mucous membranes. Used in organic synthesis and in lacquers and paints.
Air & Water Reactions	Flammable.
Reactivity Profile	Ethyl acetoacetate, a beta-keto ester, is more reactive than many esters. Undergoes an exothermic cleavage reaction in the presence of concentrated base. Reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Mixing with 2,2,2-tris(bromomethyl)ethanol and zinc led to an explosion [US Patent 3 578 619, Crotonaldehyde may rapidly polymerize with Ethyl acetoacetate (Soriano, D.S. et al. 1988. Journal of Chemical Education 65:637.).1971].
Health Hazard	Liquid may cause mild irritation of eyes.

Ethyl acetoacetate Preparation Products And Raw materials

Raw materials

Etanol-->Sodium-->Sodium ethoxide-->Acetyl ketene-->METHANE

Preparation Products

2,4-DIMETHYLQUINOLINE-3-CARBOXYLIC ACID-->4-CHLORO-2,6-DIMETHYL-NICOTINIC ACID-->ETHYL 2-HYDROXY-4-METHYL-5-PYRIMIDINECARBOXYLATE-->BISPYRAZOLONE-->ETHYL 4-CHLORO-2,6-DIMETHYLPYRIDINE-3-CARBOXYLATE-->TIADINIL-->1-Bromo-5-hexanone-->3-CHLORO-4-METHYL-7-HYDROXYCOUNMARIN-->5,7-Dihydroxy-4-methylcoumarin-->5-METHYL-1-PHENYL-1H-PYRAZOLE-4-CARBOXYLIC ACID-->7,8-DIHYDROXY-4-METHYLCOUMARIN-->6-TERT-BUTYL-4-METHYLCOUMARIN-->2-Amino-6-methyl-4-pyrimidinol-->4,7-DIMETHYLCOUMARIN-->1,3-Dimethyl-5-hydroxypyrazole-->4-Chloro-6-methyl-2-(methylthio)pyrimidine-->(5-METHYL-1-PHENYL-1H-PYRAZOL-4-YL)METHANOL-->7-Acetoxy-4-methylcoumarin-->Pentoxifylline-->4-Methylumbelliferone-->Disperse Yellow H-4GL-->ETHYL 2,4-DIMETHYLQUINOLINE-3-CARBOXYLATE-->3-METHYL-5-PHENYL-4-ISOXAZOLECARBOXYLIC ACID-->PHENOXYACETIC ACID-->Chrysin-->Cloricromene-->ethyl 2-[2-(diethylamino)ethyl]acetoacetate -->ETHYL 5-METHYL-1-PHENYL-1H-PYRAZOLE-4-CARBOXYLATE-->6-Methyl-2-(methylthio)pyrimidin-4-ol-->ETHYL 2-ACETYL-3-OXO-HEXANOATE-->4-HYDROXY-2-METHYLQUINOLINE-->3-ETHOXYCARBONYL-5,6-DIHYDRO-2-METHYL-4H-PYRAN-->1-(6-CHLORO-2-HYDROXY-4-PHENYL-QUINOLIN-3-YL)-ETHANONE-->4-Methylcumarin-->Acetoacetic Acid-->Ethyl 3-anilinobut-2-enoate-->Ethyl 3-hydroxybutyrate-->ETHYL 2-(HYDROXYIMINO)-3-OXOBUTANOATE-->N-Phenylglycine potassium salt-->3-Ethyl-4-methyl-3-pyrrolin-2-one

Details

Ethyl acetoacetate Basic information

Product Name:	Ethyl acetoacetate
Synonyms:	FEMA 2415;LABOTEST-BB LT01690211;EAA;ETHYL 3-OXOBUTANATE;ETHYL 3-OXOBUTANOATE;ETHYL 3-OXOBUTANOIC ACID;ETHYL 3-OXOBUTYRATE;ETHYL 3-KETOBUTANOATE
CAS:	141-97-9
MF:	C6H10O3
MW:	130.14
EINECS:	205-516-1
Product Categories:	Pharmaceutical Intermediates;Organics;API intermediates;Miscellaneous;ester Flavor;Analytical Reagents;Analytical Reagents for General Use;Analytical/Chromatography;Building Blocks;C6 to C7;Carbonyl Compounds;Chemical Synthesis;E-H;Esters;Organic Building Blocks;Puriss p.a.;Organic synthesis;Solvent
Mol File:	141-97-9.mol

Ethyl acetoacetate Chemical Properties

mp	−43 °C(lit.)
bp	181 °C(lit.)
density	1.029 g/mL at 20 °C(lit.)
vapor density	4.48 (vs air)
vapor pressure	1 mm Hg ( 28.5 °C)
refractive index	n20/D 1.419
FEMA	2415
Fp	185 °F
solubility	116 g/L (20°C)
Water Solubility	116 g/L (20 ºC)
Merck	14,3758
BRN	385838
Stability:	Stable. Incompatible with acids, bases, oxidizing agents, reducing agents, alkali metals. Combustible.
CAS DataBase Reference	141-97-9(CAS DataBase Reference)
NIST Chemistry Reference	Butanoic acid, 3-oxo-, ethyl ester(141-97-9)
EPA Substance Registry System	Butanoic acid, 3-oxo-, ethyl ester(141-97-9)

Safety Information

Hazard Codes	Xi
Risk Statements	36
Safety Statements	26-24/25
RIDADR	UN 1993
WGK Germany	1
RTECS	AK5250000
HazardClass	3.2
PackingGroup	III
Hazardous Substances Data	141-97-9(Hazardous Substances Data)

MSDS Information

Provider	Language
Acetoacetic ester	English
SigmaAldrich	English
ACROS	English
ALFA	English

Ethyl acetoacetate Usage And Synthesis

Chemical Properties	Colourless, clear liquid
Usage	Ethyl acetoacetate (EAA) is used as starting material for the syntheses of alpha-substituted acetoacetic esters and cyclic compounds, e.g. pyrazole, pyrimidine and coumarin derivatives as well as intermediate for vitamins and pharmaceuticals. Product Data Sheet
General Description	A colorless liquid with a fruity odor. Flash point 185°F. Boiling point 365°F. May cause adverse health effects if ingested or inhaled. May irritate to skin, eyes and mucous membranes. Used in organic synthesis and in lacquers and paints.
Air & Water Reactions	Flammable.
Reactivity Profile	Ethyl acetoacetate, a beta-keto ester, is more reactive than many esters. Undergoes an exothermic cleavage reaction in the presence of concentrated base. Reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Mixing with 2,2,2-tris(bromomethyl)ethanol and zinc led to an explosion [US Patent 3 578 619, Crotonaldehyde may rapidly polymerize with Ethyl acetoacetate (Soriano, D.S. et al. 1988. Journal of Chemical Education 65:637.).1971].
Health Hazard	Liquid may cause mild irritation of eyes.

Ethyl acetoacetate Preparation Products And Raw materials

Raw materials

Etanol-->Sodium-->Sodium ethoxide-->Acetyl ketene-->METHANE

Preparation Products

2,4-DIMETHYLQUINOLINE-3-CARBOXYLIC ACID-->4-CHLORO-2,6-DIMETHYL-NICOTINIC ACID-->ETHYL 2-HYDROXY-4-METHYL-5-PYRIMIDINECARBOXYLATE-->BISPYRAZOLONE-->ETHYL 4-CHLORO-2,6-DIMETHYLPYRIDINE-3-CARBOXYLATE-->TIADINIL-->1-Bromo-5-hexanone-->3-CHLORO-4-METHYL-7-HYDROXYCOUNMARIN-->5,7-Dihydroxy-4-methylcoumarin-->5-METHYL-1-PHENYL-1H-PYRAZOLE-4-CARBOXYLIC ACID-->7,8-DIHYDROXY-4-METHYLCOUMARIN-->6-TERT-BUTYL-4-METHYLCOUMARIN-->2-Amino-6-methyl-4-pyrimidinol-->4,7-DIMETHYLCOUMARIN-->1,3-Dimethyl-5-hydroxypyrazole-->4-Chloro-6-methyl-2-(methylthio)pyrimidine-->(5-METHYL-1-PHENYL-1H-PYRAZOL-4-YL)METHANOL-->7-Acetoxy-4-methylcoumarin-->Pentoxifylline-->4-Methylumbelliferone-->Disperse Yellow H-4GL-->ETHYL 2,4-DIMETHYLQUINOLINE-3-CARBOXYLATE-->3-METHYL-5-PHENYL-4-ISOXAZOLECARBOXYLIC ACID-->PHENOXYACETIC ACID-->Chrysin-->Cloricromene-->ethyl 2-[2-(diethylamino)ethyl]acetoacetate -->ETHYL 5-METHYL-1-PHENYL-1H-PYRAZOLE-4-CARBOXYLATE-->6-Methyl-2-(methylthio)pyrimidin-4-ol-->ETHYL 2-ACETYL-3-OXO-HEXANOATE-->4-HYDROXY-2-METHYLQUINOLINE-->3-ETHOXYCARBONYL-5,6-DIHYDRO-2-METHYL-4H-PYRAN-->1-(6-CHLORO-2-HYDROXY-4-PHENYL-QUINOLIN-3-YL)-ETHANONE-->4-Methylcumarin-->Acetoacetic Acid-->Ethyl 3-anilinobut-2-enoate-->Ethyl 3-hydroxybutyrate-->ETHYL 2-(HYDROXYIMINO)-3-OXOBUTANOATE-->N-Phenylglycine potassium salt-->3-Ethyl-4-methyl-3-pyrrolin-2-one

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141-97-9 C6H10O3 Ethyl acetoacetate

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