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Acetone oxime

CAS NO.127-06-0

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Keywords

  • 127-06-0 LABOTEST-BB LT00516122
  • HIGH purity by own lab 126-91-0
  • Pharmaceutical Intermediates;Oximino Silanes;Nitrogen Compounds;Organic Building Blocks;Oximes

Quick Details

  • ProName: Acetone oxime
  • CasNo: 127-06-0
  • Molecular Formula: C10H18O
  • Appearance: White crystals
  • Application: 127-06-0
  • DeliveryTime: Within 7 working days since received y...
  • PackAge: 1g;5g;10g;25g;50g;100g;500g;1KG;5KG,25...
  • Port: Any Chinese main ports
  • ProductionCapacity: 100 Kilogram/Month
  • Purity: 99%
  • Storage: 2-8, cold storage, to avoid light stor...
  • Transportation: BY SEA /BY AIR /BY COURIER
  • LimitNum: 100 Gram
  • Heavy metal: NULL
  • Grade: Industrial Grade,Food Grade,Pharma Gra...
  • Valid Period: 6 month
  • Application: Multipurpose intermediate
  • Certification: ISO/9001 Certificate

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Acetone oxime Basic information
Physical and Chemical Properties chemical reaction
Product Name: Acetone oxime
Synonyms: (CH3)2C=NOH;2-Propanonoxime;Acetonoxime;beta-Isonitrosopropane;-iso-Nitrosopropane;propan-2-oneoxime;DI METHYL KETOXIME;LABOTEST-BB LT00516122
CAS: 127-06-0
MF: C3H7NO
MW: 73.09
EINECS: 204-820-1
Product Categories: Pharmaceutical Intermediates;Oximino Silanes;Nitrogen Compounds;Organic Building Blocks;Oximes
Mol File: 127-06-0.mol
Acetone oxime Structure
 
Acetone oxime Chemical Properties
mp  60-63 °C(lit.)
bp  135 °C(lit.)
density  0.901 g/mL at 25 °C(lit.)
Fp  60 °C
Water Solubility  330 g/L (20 ºC)
Merck  14,75
BRN  1560146
CAS DataBase Reference 127-06-0(CAS DataBase Reference)
NIST Chemistry Reference 2-Propanone, oxime(127-06-0)
EPA Substance Registry System 2-Propanone, oxime(127-06-0)
 
Safety Information
Safety Statements  22-24/25
RIDADR  UN1325
WGK Germany  3
RTECS  AL6825000
21
HazardClass  4.1
PackingGroup  III
MSDS Information
Provider Language
2-Propanone oxime English
ACROS English
SigmaAldrich English
ALFA English
 
Acetone oxime Usage And Synthesis
Physical and Chemical Properties Acetone oxime (Abbreviation DMKO for short), also known as dimethyl ketone oxime, is a white flaky crystal at room temperature, relative density: 0.9113, melting point: 60 ℃, flash point: 47.2 ℃, boiling point: 134.8 ℃, toxicity LD50: 5500mg / kg. It is soluble in water and alcohol, ether and other solvents, saturated aqueous solubility is 25% (mass percentage), its aqueous solution is neutral, it hydrolyzes easily in dilute acid, can make potassium permanganate fading at room temperature. Mainly used as chemical oxygen scavenger for industrial boiler feed water, compared with the traditional boiler chemical oxygen scavenger, it has characteristics of less dosage, high oxygen removal efficiency, non-toxic, pollution-free. It is the best drug for the outage protection and passivation treatment of subcritical boiler, also is the ideal products of substituted hydrazine and other traditional chemical oxygen scavengers in medium and high pressure boiler feed water. 
the molecular structure of Acetone oxime
Figure 1 the molecular structure of Acetone oxime.
chemical reaction Acetone oxime has a strong reduction, it is easy to react with oxygen in water to reduce the dissolved oxygen content in water, reaction is as follows: 
2C3H7NO + O2 → 2C3H6CO + N2O + H2O and 4 (CH3) 2C = N-OH + O2 → 4 (CH3) 2C = O + 2N2 + H2O Meanwhile, Acetoxime also reacts with the metal for passivation, reaction is as follows: 2C3H7NO + 6Fe2O3 → 2C3H6CO + N2O + 4Fe3O4 + H2O Acetoxime can reduce the content of iron in the feed water, to prevent overheating of the metal pipe and corrosion damage of the boiler due to the formation of iron oxide deposits, while with the cleaning effect for copper corrosion products deposited on pipes, economizer, etc. This is the reason that in the early use of acetone oxime, the content of copper in boiler water will be significantly higher. Decomposition products of Acetoxime are mainly nitrogen and water, a small amount of formic acid, acetic acid, nitrogen oxides and so on. On the premise of ensuring oxygen removal effect, when the residual amount of DMKO in feed water is controlled to be 5 ~ 40μg / L, the formic acid, acetic acid, Cl-, SO42 + was not detected in all tested samples of water vapor, at the same time NO2- and NO3- content of same samples were tested, are also not detected. Therefore, there is no any adverse effects for the use of acetone oxime oxygen in vapor system.
Chemical Properties White crystals

 

 

 

 

 

 

 

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