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CAS NO.111-96-6
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| 2-Methoxyethyl ether Basic information |
| Product Name: | 2-Methoxyethyl ether |
| Synonyms: | DIMETHYLDIGLYCOL;DIMETHYL DIGOL;DIMETHYL CARBITOL;DIETHYLENE GLYCOL DIMETHYL ETHER;DIGLYME;'DIGLYME';DEDM;BIS(2-METHOXYETHYL) ETHER |
| CAS: | 111-96-6 |
| MF: | C6H14O3 |
| MW: | 134.17 |
| EINECS: | 203-924-4 |
| Product Categories: | Functional Materials;Plasticizer;Polyalcohol Ethers, Esters (Plasticizer);Aliphatics;Carbon Steel Cans with NPT Threads;Semi-Bulk Solvents;ACS and Reagent Grade Solvents;Amber Glass Bottles;ReagentPlus;ReagentPlus Solvent Grade Products;Solvent Bottles;Solvent by Application;Solvent Packaging Options;Solvents;Anhydrous Solvents;Sure/Seal Bottles;NMR;Spectrophotometric Grade;Spectrophotometric Solvents;Spectroscopy Solvents (IR;UV/Vis);solvent,metal organic compound synthesis |
| Mol File: | 111-96-6.mol |
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| 2-Methoxyethyl ether Chemical Properties |
| mp | −64 °C(lit.) |
| bp | 162 °C(lit.) |
| density | 0.943 g/mL at 25 °C(lit.) |
| vapor density | 4.6 (vs air) |
| vapor pressure | 3 mm Hg ( 20 °C) |
| refractive index |
n |
| Fp | 134.6 °F |
| storage temp. | Flammables area |
| color | ≤10(APHA) |
| Water Solubility | Miscible |
| Sensitive | Hygroscopic |
| Merck | 14,3165 |
| BRN | 1736101 |
| Stability: | Stable. Combustible. Incompatible with strong oxidizing agents. May be air or light sensitive. |
| CAS DataBase Reference | 111-96-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Ethane, 1,1'-oxybis[2-methoxy-(111-96-6) |
| EPA Substance Registry System | Ethane, 1,1'-oxybis[2-methoxy- (111-96-6) |
| Safety Information |
| Hazard Codes | T |
| Risk Statements | 60-61-10-19 |
| Safety Statements | 53-45 |
| RIDADR | UN 3271 3/PG 3 |
| WGK Germany | 1 |
| RTECS | KN3339000 |
| F | 3-10-23 |
| HazardClass | 3 |
| PackingGroup | III |
| Hazardous Substances Data | 111-96-6(Hazardous Substances Data) |
| 2-Methoxyethyl ether Usage And Synthesis |
| Chemical Properties | Colorless clear liquid |
| Usage | Solvent; it is used as reaction medium for Grignard and similar synthesis. |
| General Description | Colorless watery liquid with a pleasant odor. Floats and mixes with water. |
| Air & Water Reactions | Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. A mixture of liquid air and diethyl ether exploded spontaneously, [MCA Case History 616(1960)]. Water soluble. |
| Reactivity Profile | A violent explosion occurred when lithium aluminum hydride was being used to dry 2-Methoxyethyl ether. The ignition may have occurred due to the presence of large amounts of water or perhaps peroxide formed in the ether. About 75% of the ether had been removed when the explosion occurred, [MCA Case History 1494 (1968)]. |
| Health Hazard | INGESTION (severe cases): nausea, vomiting, abdominal cramps, weakness progressing to coma. |
| Fire Hazard | 2-Methoxyethyl ether is combustible. |