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Tributylphosphane

CAS NO.998-40-3

  • Min.Order: 1 Kilogram
  • Payment Terms: L/C,D/A,D/P,T/T,Other
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Product Details

Keywords

  • PHOSPHORUS TRI-N-BUTYL
  • PHOSPHINE, TRIBUTYL
  • TBUP;tris(butyl)phosphine

Quick Details

  • ProName: Tributylphosphane
  • CasNo: 998-40-3
  • Molecular Formula: C12H27P
  • Appearance: Clear liquid
  • Application: 998-40-3
  • DeliveryTime: 7-10days after payment
  • PackAge: as customer's requirement
  • Port: China main port
  • ProductionCapacity: 100-200 Kilogram/Month
  • Purity: 99%
  • Storage: 2-8°C
  • Transportation: air or sea express
  • LimitNum: 1 Kilogram

Superiority

Product Name: Tributylphosphane
Synonyms: PHOSPHORUS TRI-N-BUTYL;PHOSPHINE, TRIBUTYL;TBUP;tris(butyl)phosphine;TRI-N-BUTYLPHOSPHINE;tributylphosphane;TRIBUTYLPHOSPHINE;(n-C4H9)3P
CAS: 998-40-3
MF: C12H27P
MW: 202.32
EINECS: 213-651-2
Product Categories: Tertiary Phosphines;Ligand;Mitsunobu Reaction;Phosphine Ligands;Phosphines (Mitsunobu Reaction);Synthetic Organic Chemistry;organophosphorus ligand;organophosphine ligand;Catalysis and Inorganic Chemistry;Chemical Synthesis;Phosphine Compounds
Mol File: 998-40-3.mol
Tributylphosphane Structure
 
Tributylphosphane Chemical Properties
mp  -65 °C
bp  150 °C50 mm Hg(lit.)
density  0.81 g/mL at 25 °C(lit.)
vapor density  9 (vs air)
refractive index  n20/D 1.462(lit.)
Fp  99 °F
storage temp.  2-8°C
form  liquid
Water Solubility  insoluble
Sensitive  Moisture Sensitive/Air Sensitive
BRN  1738261
Stability: Stable, but pyrophoric - spontaneously inflammable in air. Incompatible with oxidizing agents. Moisture sensitive.
CAS DataBase Reference 998-40-3(CAS DataBase Reference)
NIST Chemistry Reference Phosphine, tributyl-(998-40-3)
EPA Substance Registry System Phosphine, tributyl-(998-40-3)
 
Safety Information
Hazard Codes  Xi,F,C,T
Risk Statements  36/38-34-21/22-17-11-37-36/37/38-61
Safety Statements  41-36/37/39-26-16-45-43-17-5-53
RIDADR  UN 3254 4.2/PG 1
WGK Germany  3
RTECS  SZ3270000
F  10-13-23
HazardClass  4.2
PackingGroup  I
MSDS Information
Provider Language
TBUP English
ACROS English
SigmaAldrich English
ALFA English
 
Tributylphosphane Usage And Synthesis
Chemical Properties Clear liquid
Usage 1,4-addition catalyst; used with disulfides for the thioetherification of alcohols; acylation catalyst; used to prepare active esters.
Usage suzuki reaction
General Description Tributylphosphane is a colorless to yellowish liquid with a strong garlic-like odor. Tributylphosphane is insoluble in water. Tributylphosphane is liable to heat and ignite spontaneously in air. If involved in a fire phosphine gas, a highly flammable and toxic gas, will evolve. Tributylphosphane is irritating to mucous membranes.
Air & Water Reactions Highly flammable. May ignite on contact with air or moist air. Insoluble in water.
Reactivity Profile Organophosphates, such as Tributylphosphane, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
Health Hazard Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
Fire Hazard Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.
 
Tributylphosphane Preparation Products And Raw materials
Preparation Products ORNOPROSTIL-->CYANOMETHYLENETRIBUTYLPHOSPHORANE-->TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE-->Cetyltributylphosphonium bromide
Raw materials Diethyl ether-->Magnesium-->Phosphorus trichloride-->1-Bromobutane
1.Certificate Of Analysis (COA)
2.Material Safety Data Sheet (MSDS)
3.Route of synthesis (ROS)
4.Method of Aanlysis(MOA)
5.Nuclear Magnetic Resonance(NMR)
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9.Factory audit
10.Strong after-sale service

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2. Prompt shipment with professional documents
3. Packing as your request, with photo before shipment
4. We can provide mixed containers with different mixed items in one container
 
HenNan sunlake enterprise corporation is located in Henan Province , The central plain of China , Which enjoys favorable geogeaphical position and convenient transportion, The com[any was established in june. 1998 , until now having more than 18 years experience in manufacturing & exporting chemical raw material .
     Sunlake is a professional manufacturer engaged in producing and selling chemicals,including Organic & inorganic chemicals , pigments & Dyestuffs ,  Water treatment chemicals , Food & FEED additives and others . these products have been being well exported to europe , southeast Asia , the Middle East ,  Africa , South America and some other countries and areas.
    We sincerely welcome foreign friends to visit our plant for cooperation. With the idea of "quality first,credit priority, Excellent service", We are highly acknowledged by customers for good quality and competitive price. More importantly , the company has a strong R & D team, who are professional engineers and scholars with Ph. D. .So we are confident to serve you  better with our high - quality products and professional team.
    We are taking great efforts to provide our customers with demanded goods and professional services, and continuously improve our core ability of competition and get the momentum for sustainable development, and finally make us being a reliable and professional wupplier in international market.
     We  welcome any serious inquiries from all customers of the world, and sincerely hope to cooperate with you for a brilliant future!

 

Details

 
Product Name: Tributylphosphane
Synonyms: PHOSPHORUS TRI-N-BUTYL;PHOSPHINE, TRIBUTYL;TBUP;tris(butyl)phosphine;TRI-N-BUTYLPHOSPHINE;tributylphosphane;TRIBUTYLPHOSPHINE;(n-C4H9)3P
CAS: 998-40-3
MF: C12H27P
MW: 202.32
EINECS: 213-651-2
Product Categories: Tertiary Phosphines;Ligand;Mitsunobu Reaction;Phosphine Ligands;Phosphines (Mitsunobu Reaction);Synthetic Organic Chemistry;organophosphorus ligand;organophosphine ligand;Catalysis and Inorganic Chemistry;Chemical Synthesis;Phosphine Compounds
Mol File: 998-40-3.mol
Tributylphosphane Structure
 
Tributylphosphane Chemical Properties
mp  -65 °C
bp  150 °C50 mm Hg(lit.)
density  0.81 g/mL at 25 °C(lit.)
vapor density  9 (vs air)
refractive index  n20/D 1.462(lit.)
Fp  99 °F
storage temp.  2-8°C
form  liquid
Water Solubility  insoluble
Sensitive  Moisture Sensitive/Air Sensitive
BRN  1738261
Stability: Stable, but pyrophoric - spontaneously inflammable in air. Incompatible with oxidizing agents. Moisture sensitive.
CAS DataBase Reference 998-40-3(CAS DataBase Reference)
NIST Chemistry Reference Phosphine, tributyl-(998-40-3)
EPA Substance Registry System Phosphine, tributyl-(998-40-3)
 
Safety Information
Hazard Codes  Xi,F,C,T
Risk Statements  36/38-34-21/22-17-11-37-36/37/38-61
Safety Statements  41-36/37/39-26-16-45-43-17-5-53
RIDADR  UN 3254 4.2/PG 1
WGK Germany  3
RTECS  SZ3270000
F  10-13-23
HazardClass  4.2
PackingGroup  I
MSDS Information
Provider Language
TBUP English
ACROS English
SigmaAldrich English
ALFA English
 
Tributylphosphane Usage And Synthesis
Chemical Properties Clear liquid
Usage 1,4-addition catalyst; used with disulfides for the thioetherification of alcohols; acylation catalyst; used to prepare active esters.
Usage suzuki reaction
General Description Tributylphosphane is a colorless to yellowish liquid with a strong garlic-like odor. Tributylphosphane is insoluble in water. Tributylphosphane is liable to heat and ignite spontaneously in air. If involved in a fire phosphine gas, a highly flammable and toxic gas, will evolve. Tributylphosphane is irritating to mucous membranes.
Air & Water Reactions Highly flammable. May ignite on contact with air or moist air. Insoluble in water.
Reactivity Profile Organophosphates, such as Tributylphosphane, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
Health Hazard Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
Fire Hazard Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.
 
Tributylphosphane Preparation Products And Raw materials
Preparation Products ORNOPROSTIL-->CYANOMETHYLENETRIBUTYLPHOSPHORANE-->TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE-->Cetyltributylphosphonium bromide
Raw materials Diethyl ether-->Magnesium-->Phosphorus trichloride-->1-Bromobutane

 

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