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CAS NO.38721-52-7
| Lithium triisobutylhydroborate Basic information |
| Product Name: | Lithium triisobutylhydroborate |
| Synonyms: | LITHIUM TRI-S-BUTYLHYDROBORATE;LITHIUM TRI-SEC-BUTYLBOROHYDRIDE;LITHIUM TRI-SEC-BUTYLHYDRIDOBORATE;LITHIUM TRIISOBUTYLHYDROBORATE;L-SELECTRIDE(R);lithium,(beta-4)-borate(1-hydrotris(1-methylpropyl)-;lithiumtri-sec-butylborohydride,calselect li,;lithiumtri-sec-butylborohydride,calselect li,intetrahydrofuran |
| CAS: | 38721-52-7 |
| MF: | C12H28BLi |
| MW: | 190.1 |
| EINECS: | 254-101-1 |
| Product Categories: | B (Classes of Boron Compounds);Classes of Metal Compounds;Li (Lithium) Compounds;Reduction;Synthetic Organic Chemistry;Tetrahydroborates;Typical Metal Compounds |
| Mol File: | 38721-52-7.mol |
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| Lithium triisobutylhydroborate Chemical Properties |
| density | 0.89 g/mL at 25 °C |
| Fp | 1 °F |
| storage temp. | Flammables area |
| Water Solubility | reacts |
| Sensitive | Moisture Sensitive |
| BRN | 4007327 |
| CAS DataBase Reference | 38721-52-7(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | F,C |
| Risk Statements | 11-14/15-17-34-35-19-40-37 |
| Safety Statements | 16-26-36/37/39-43-45-7/8-30 |
| RIDADR | UN 3394 4.2/PG 1 |
| WGK Germany | 1 |
| F | 10 |
| HazardClass | 4.3 |
| PackingGroup | II |
| Lithium triisobutylhydroborate Usage And Synthesis |
| Chemical Properties | clear colourless solution |
| Usage | Reducing agent. Reagent for: Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters. Diastereoselective reduction reactions. Hydride reduction of the Danishefsky pyranones. Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes. Synthesis of alkanols by carbonylation reactions. |
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