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CAS NO.333-27-7
|
| Methyl trifluoromethanesulfonate Basic information |
| Product Name: | Methyl trifluoromethanesulfonate |
| Synonyms: | Methanesulfonicacid,trifluoro-,methylester;methyltrifluoromethanesulfinate;trifluoromethane-sulfinicacid,methylester;trifluoro-methanesulfonicacimethylester;METHYL TRIFLUOROMETHANESULPHONATE;METHYL TRIFLUOROMETHANESULFONATE;METHYL TRIFLATE;TRIFLUOROMETHANESULFONIC ACID METHYL ESTER |
| CAS: | 333-27-7 |
| MF: | C2H3F3O3S |
| MW: | 164.1 |
| EINECS: | 206-371-7 |
| Product Categories: | |
| Mol File: | 333-27-7.mol |
|
|
|
| Methyl trifluoromethanesulfonate Chemical Properties |
| bp | 94-99 °C(lit.) |
| density | 1.45 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Fp | 101 °F |
| storage temp. | 0-6°C |
| CAS DataBase Reference | 333-27-7(CAS DataBase Reference) |
| EPA Substance Registry System | Methanesulfonic acid, trifluoro-, methyl ester(333-27-7) |
| Safety Information |
| Hazard Codes | C,T |
| Risk Statements | 10-34-20/21/22 |
| Safety Statements | 26-36/37/39-45-16 |
| RIDADR | UN 2920 8/PG 2 |
| WGK Germany | 3 |
| F | 10 |
| Hazard Note | Highly Toxic/Corrosive |
| TSCA | T |
| HazardClass | 3.2 |
| PackingGroup | III |
| HS Code | 29049020 |
| MSDS Information |
| Provider | Language |
|---|---|
| Methyl trifluoromethanesulfonate | English |
| SigmaAldrich | English |
| ACROS | English |
| Methyl trifluoromethanesulfonate Usage And Synthesis |
| Chemical Properties | clear colourless to yellow liquid |
| Usage | suzuki reaction |
| General Description | Brown liquid. Insoluble in water. |
| Air & Water Reactions | Highly flammable. Insoluble in water. |
| Reactivity Profile | Methyl trifluoromethanesulfonate is sensitive to heat. . Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. |
| Health Hazard | ACUTE/CHRONIC HAZARDS: When heated to decomposition Methyl trifluoromethanesulfonate emits toxic fumes. |
| Fire Hazard | Methyl trifluoromethanesulfonate is combustible. |
| Methyl trifluoromethanesulfonate Preparation Products And Raw materials |
| Raw materials | Methanol-->Thionyl chloride-->Dimethyl sulfate-->Trifluoromethanesulfonic acid |
|
| Methyl trifluoromethanesulfonate Basic information |
| Product Name: | Methyl trifluoromethanesulfonate |
| Synonyms: | Methanesulfonicacid,trifluoro-,methylester;methyltrifluoromethanesulfinate;trifluoromethane-sulfinicacid,methylester;trifluoro-methanesulfonicacimethylester;METHYL TRIFLUOROMETHANESULPHONATE;METHYL TRIFLUOROMETHANESULFONATE;METHYL TRIFLATE;TRIFLUOROMETHANESULFONIC ACID METHYL ESTER |
| CAS: | 333-27-7 |
| MF: | C2H3F3O3S |
| MW: | 164.1 |
| EINECS: | 206-371-7 |
| Product Categories: | |
| Mol File: | 333-27-7.mol |
|
|
|
| Methyl trifluoromethanesulfonate Chemical Properties |
| bp | 94-99 °C(lit.) |
| density | 1.45 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Fp | 101 °F |
| storage temp. | 0-6°C |
| CAS DataBase Reference | 333-27-7(CAS DataBase Reference) |
| EPA Substance Registry System | Methanesulfonic acid, trifluoro-, methyl ester(333-27-7) |
| Safety Information |
| Hazard Codes | C,T |
| Risk Statements | 10-34-20/21/22 |
| Safety Statements | 26-36/37/39-45-16 |
| RIDADR | UN 2920 8/PG 2 |
| WGK Germany | 3 |
| F | 10 |
| Hazard Note | Highly Toxic/Corrosive |
| TSCA | T |
| HazardClass | 3.2 |
| PackingGroup | III |
| HS Code | 29049020 |
| MSDS Information |
| Provider | Language |
|---|---|
| Methyl trifluoromethanesulfonate | English |
| SigmaAldrich | English |
| ACROS | English |
| Methyl trifluoromethanesulfonate Usage And Synthesis |
| Chemical Properties | clear colourless to yellow liquid |
| Usage | suzuki reaction |
| General Description | Brown liquid. Insoluble in water. |
| Air & Water Reactions | Highly flammable. Insoluble in water. |
| Reactivity Profile | Methyl trifluoromethanesulfonate is sensitive to heat. . Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. |
| Health Hazard | ACUTE/CHRONIC HAZARDS: When heated to decomposition Methyl trifluoromethanesulfonate emits toxic fumes. |
| Fire Hazard | Methyl trifluoromethanesulfonate is combustible. |
| Methyl trifluoromethanesulfonate Preparation Products And Raw materials |
| Raw materials | Methanol-->Thionyl chloride-->Dimethyl sulfate-->Trifluoromethanesulfonic acid |