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CAS NO.12354-85-7
1(10-100)Metric Ton1(10-100)Metric Ton
| Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Basic information |
| Product Name: | Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] |
| Synonyms: | Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium;Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE;DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER;BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM];PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)& |
| CAS: | 12354-85-7 |
| MF: | C20H30Cl4Rh2 10* |
| MW: | 618.08 |
| EINECS: | |
| Product Categories: | Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium;metallocene;NULL |
| Mol File: | 12354-85-7.mol |
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| Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties |
| mp | >300°C |
| NIST Chemistry Reference | Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7) |
| Safety Information |
| Hazard Codes | Xn |
| Risk Statements | 20/21/22-36/37/38-R36/37/38-R20/21/22 |
| Safety Statements | 26-36-S36-S26 |
| WGK Germany | 3 |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Usage And Synthesis |
| Chemical Properties | burgundy solid |
| Usage | Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A |
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